Each of the eight principles supports or contributes to interoperability in some manner. Therefore, in relation to service-oriented computing, stating that services must be interoperable is just about as evident as stating that services must exist. Dieckmann condensation and retro-Claisen condensationġ5-3.One item that may appear to be absent from the preceding list is a principle along the lines of “Services are Interoperable.” The reason this does not exist as a separate principle is because interoperability is fundamental to every one of the principles we just described. Enol and Enolate reactions (aldehydes and ketones) 14-1. Supplementary: Acid-catalyzed hydrolysis of tert-butyl estersġ3-7. Synthetic method for esters-2: Methyl ester formation by diazomethaneġ3-4. Synthetic method for esters-1: Fischer esterificationġ3-2. Supplementary: Addition of Grignard reagents to carbon dioxideġ3. Addition of primary amines: Imine formationġ2-6. Addition of alcohols: Hemiacetal and acetal formationġ2-4. Nucleophilic addition to carbonyl groupġ2-3. Nucleophilic addition to carbonyl group (aldehydes and ketones) 12-1. Nucleophilic opening of epoxides with Grignard reagentsġ2. Supplementary: Removal of methyl protecting groupġ1-5. Acid cleavage of ethers: Reaction with acidsġ1-4. Synthesis of ethers-2: Williamson Ether Synthesisġ1-3. Supplementary: Saytzeff’s rule (Zaitsev’s rule)ġ1. Supplementary: Allyllic rearrangementġ0-6. Acid-catalyzed elimination of water (Dehydration)ġ0-5. Elimination reaction (E2 and E1) of alkyl halides 9-1. Nucleophilic substitution (SN2 and SN1) of alkyl halides 8-1. Nitrobenzene: m-directing and deactivatingĨ. Phenol: o,p-directing and activatingħ-7-3. Toluene: o,p-directing and activatingħ-7-2. Electrophilic substitution of benzene derivatives 7-6-1. Summary of electrophilic aromatic substitutionħ-6. Sulfonation: Sulfonation is reversible !ħ-4. Alkyne addition reactions: Electrophilic addition 6-1. Reaction with hydrogen (Catalytic hydrogenation)Ħ.
Reaction with osmium tetroxide: Dihydroxidationĥ-11.
Reaction with peroxyacid (peracid): Epoxidation 5-9.
Addition of halogen (Halogenation): Brominationĥ-8. Reaction mechanism (How to draw curved arrows)ĥ-7. Acid catalyzed addition of water (Hydration)ĥ-4. Supplementary: Rearrangement reactionĥ-4. Alkene addition reactions: Electrophilic additions 5-1. Halogenation of alkanes (Radical reaction)ĥ. Types of arrows used in organic chemistryĤ. Mastering basic reaction mechanisms is an important survival skill for students learning organic chemistry.ġ. Organic Chemistry Reaction Mechanism is a useful App for learning the fundamentals of reaction mechanism in organic chemistry by using curved arrows. You can switch between English and Japanese freely. You can study organic chemistry, how to write curved arrows, with 106 videos while listening to your favorite music.
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